As a msds service provider, we are specialists in ghs. Signal word danger hazard statements h225 highly flammable liquid and vapour. Workers whose clothing has been contaminated by toluene2,4diisocyanate should change into clean clothing promptly. Exposure to benzene, toluene, ethylbenzene, xylene.
Toluene is listed in the tsca inventory and in sara 3. Reacts chemically with nitrogen oxides, or halogens to form nitrotoluene, nitrobenzene, and. Chronic hydrocarbon abuse for example, sniffing glue or light hydrocarbons such as contained in this material has been associated. Identification of the substancemixture and of the companyundertaking. Add known amounts of toluene to cs2 in 10ml volumetric flasks and dilute to the mark to produce toluene concentrations in the range 0. Toluene can also be used as a recreational inhalant sometimes, and it also has the potential of causing severe neurological harm.
Msds examples sds sheets msds authoring services inc. It is also used as a precursor for synthesizing benzene. Toluene is used in making paints, paint thinners, fingernail polish, lacquers, adhesives, and rubber and in. Msds authoring services specialize in msds writing, creation, development and authoring. Hazardous combustion products hazardous decomposition products formed under fire conditions.
Analyze with samples and blanks steps 8 through 10. Toluene 1 material safety data sheet sciencelab air. Toluene safety in the workplace occupational safety and. However, the information is provided without any warranty, express.
Identification of the substancemixture and of the companyundertaking 1. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Safety data sheet according to 29cfr19101200 and ghs rev. Toluene, also known as methylbenzene, phenylmethane or toluol is a clear, colorless liquid with a sweet smell. Safety data sheet northwest missouri state university. Other pertinent literature is also presented, but is described in less detail than the key studies. Calibrate daily with at least six working standards. Methods for cleaning up use only nonsparking tools. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Toluene is added to gasoline, used to produce benzene, and used as a solvent. The central nervous system cns is the primary target organ for toluene toxicity in both humans and animals for acute shortterm and chronic longterm exposures.
It is colorless, waterinsoluble and has a smell associated with paint thinners. The products of degradation are less toxic than the product itself. Exposure to toluene may occur from breathing ambient or indoor air affected by such sources. Osha no component of this product present at levels greater than or equal to 0. For sampling details, please see the source document. Potentially toxicirritating fumesvapors may be evolved. Toluene occurs naturally in crude oil and in the tolu tree. Material safety data sheet toluene, acs 6 cerclasara section 3. Toluene is also highly flammable and may catch on fire if exposed to heat or flames. Product ingredients section 3 of the msds ingredient cas number proportion toluol 108883 100 for further ingredients information, please refer to the full msds risk phrases section 2 of the msds r 11. The atsdr toxicological profile succinctly characterizes the toxicologic and adverse health effects information for the hazardous substance described here. Toluene is also called as toluol, is an aromatic hydrocarbon.
Product uses toluene is mainly used as a precursor in the production of other chemicals, as a solvent, or as a fuel or fuel additive. Material may produce a serious, potentially fatal pneumonia if swallowed or vomited. Material safety data sheet information for further. Toluene product safety summary exxonmobil chemical. The personal exposure concentrations of benzene, toluene, ethylbenzene, and xylene for a gas station employee were significantly higher than those for indoors and the ambient air. However, we make no warranty of merchantability or any other. Prevent exposure to ignition sources, for example use nonsparking tools and explosionproof equipment. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only.
Sigmaaldrich 244511 page 3 of 8 suitable extinguishing media use water spray, alcoholresistant foam, dry chemical or carbon dioxide. Toluene was detected in most blood samples of nonoccupationally exposed individuals with a mean level of less than 1 ppb 35. If inhaled if breathed in, move person into fresh air. Show this material safety data sheet to the doctor in attendance. All equipment used when handling the product must be grounded. Safety data sheet according to federal register vol. Toluene cas no 108883 material safety data sheet sdsmsds. Toluene safety data sheet p6240 this sds conforms to u. Skin contact wash off immediately with plenty of water for at least 15 minutes.
This material is not known or reported to be carcinogenic by any reference source including iarc, osha, ntp, or epa. Absorb spill using an absorbent, noncombustible material such as earth, sand, or vermiculite. Terminate sampling by sealing the sampler as recommended by the manufacturer or by transferring, in a toluenefree environment, the activated charcoal collection element to a vial and sealing the vial with a septum cap. Exposure controlspersonal protection the use of local exhaust ventilation is recommended to control emissions near the source. P202 do not handle until all safety precautions have been read and understood. We provide affordable low cost price quotes on quality and accurate msds and ghs services and documents.
Toluene, a flammable liquid with a pungent odor, is widely employed as an organic solvent. Toluene material safety data sheet cas no 108883 sdsmsds. Add known amounts of toluene to cs 2 in 10ml volumetric flasks and dilute to the mark to produce toluene concentrations in the range 0. It is also produced in the process of making gasoline and other fuels from crude oil and making coke from coal. Disclaimer of liability the information in this msds was obtained from sources which we believe are reliable. Section 6 accidental release measures general information. Information in this msds is from available published sources and is believed to be accurate. Exposure to toluene can cause eye and nose irritation, tiredness, confusion, euphoria, dizziness, headache, dilated pupils, tears, anxiety, muscle fatigue, insomnia, nerve damage. It dissolves other substances easily and evaporates quickly into the air. Eye wash fountains should be provided in the immediate. Mean blood levels in a nonoccupationally exposed population examined by antoine et al. Page 1 of 10 safety data sheet toluene diisocyanate.
A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 psm 100x10e12 siemens per meter and is considered a semi conductive. Toluene undergoes alkylation in the presence of modified zsm zeolite socony mobil5class zeolite catalysts to form p xylene with high selectivity. Use proper personal protective equipment as indicated in section 8. Toluene2,4diamine was identified but not quantified in wastewater samples from an unspecified industry. Avoid runoff into storm sewers and ditches which lead to waterways.
Toluene diffusive sampler 4000 wikisource, the free. Product identifier product name toluene product number toen reach registration number 012119471051xxxx cas number 108883 eu index number 601021003 ec number 2036259 1. Show this safety data sheet to the doctor in attendance. Frozen bromine trifluoride reacts violently with toluene at 80 deg. Toluene2,6diisocyanate page 3 of 6 contaminated work clothes should be laundered by individuals who have been informed of the hazards of exposure to toluene2,6diisocyanate. Chemical product and company identification product name. Firstaid measures general advice if symptoms persist, call a physician. Safety data sheet toluene reference, fuel grade version 1. Bdh180 page 7 of 9 non mutagenic in ames salmonellamicrosome assay non mutagenic in cho chromosome aberration assay other data.
Toluene structure, properties, preparation and reactions. Transport information land transport us dot no data available. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. Studies with laboratory animals 3739 and humans 27 indicate that percutaneous absorption is. In case of skin contact wash off with soap and plenty of water. Laboratory samples should be handled in a fume hood. Toluene2,4diisocyanate page 3 of 6 good work practices can help to reduce hazardous exposures. Acgih no component of this product present at levels greater. Special protective equipment for firefighters wear self contained breathing apparatus for fire fighting if necessary. It is first isolated in 1837 by distillation of pine oil by a polish chemist named filip walter. Use a noncombustible material like vermiculite, sand or.
86 192 898 1009 1322 1068 976 200 2 825 161 252 1320 394 255 1465 1337 124 657 1025 802 729 1406 522 513 950 761 1469 807 214 1164 528 1424 186 1359 1078 602 1101 777 609 1161 965 428 1042